利用PtOEP掺杂改善Spiro发光器件的发光效率

为了利用有机三线态发光提高有机发光器件的发光效率,用磷光材料掺杂到聚合物主体中作为发光层,制备有机电致发光器件.在测量器件的电流-电压特性、发光亮度-电压特性和电致发光谱的基础上,计算了器件的外量子效率,研究了磷光材料的掺杂浓度对器件发光效率的影响.结果表明,对特定的材料体系,适当控制掺杂浓度,可以同时观察到荧光和磷光光谱,使掺杂器件的外量子效率在纯聚合物发光器件的基础上得到明显提高.     

太赫兹Si/SiGe量子级联激光器波导模拟

波导层结构设计是制备太赫兹(THz)量子级联激光器的关键问题之一.本文基于德鲁得(Drude)模型,利用时域有限差分(FDTD)法,对Si/SiGe量子级联激光器的波导层进行优化设计,从理论上对传统的递变折射率波导、单面金属波导、双面金属波导以及金属/金属硅化物波导横磁模(TM模)的模式损耗和光场限制因子进行了对比分析.结果表明,金属/金属硅化物波导不但可以减小波导损耗,而且有很高的光学限制因子,同时其工艺也比双面金属波导容易实现,为Si/SiGe太赫兹量子级联激光器波导层的设计提供了一定的理论指导.     

开放环境下多比特量子计算机的相干控制模型

研究了开放环境下多比特量子计算系统的相干控制建模问题.基于开放量子系统的数学模型,选取适当的矩阵基将描述多比特量子计算机的复矩阵动态控制模型转化为实向量空间上的控制模型,并给出计算相应的结构系数的方法.这些工作提供了进一步研究控制律设计的基础.     

基于宇宙量子算法的微小零件尺寸检测

通过建立主、从式宇宙空间结构改善了量子算法的运行效率,非正交二次B样条小波和最小二乘小波支持向量回归机对零件边缘进行检测,给出了微小零件尺寸检测流程。试验仿真显示该算法对微小零件尺寸测量数据波动范围较小,方差值相比其他方法值较低,其中UQ算法测量的外轮直径测量方差值比HI、MM、AIT、IF、IGR算法分别减少了75.29%,78.40%,64.47%,60.95%,52.15%;UQ算法测量的内轮直径测量方差值比HI、MM、AIT、IF、IGR算法分别减少了72.89%,76.75%,62.66%,59.22%,50.13%,提高了微小零件的精度测量。     

Fabrication of 1.55μm Si-Based Resonant Cavity Enhanced Photodetectors

A novel bonding method using silicate gel as bonding medium is developed.High reflective SiO2/Si mirrors deposited on silicon substrates by e-beam deposition are bonded to the active layers at a low temperature of 350℃ without any special treatment on bonding surfaces.The reflectivities of the mirrors can be as high as 99.9%.A Si.based narrow band response InGaAs photodetector is successfully fabricated,with a quantum efficiency of 22.6% at the peak wavelength of 1.54μm,and a full width at half maximum of about 27nm.This method has a great potential for industry processes.     

Material Growth and Device Fabrication of GaN-Based Blue-Violet Laser Diodes

Studies on first GaN-based blue-violet laser diodes(LDs) in China mainland are reported.High quality GaN materials as well as GaN-based quantum wells laser structures are grown by metal-organic chemical vapor deposition method.The X-ray double-crystal diffraction rocking curve measurements show the fullwidth half maximum of 180″ and 185″ for (0002) symmetric reflection and (10-12) skew reflection,respectively.A room temperature mobility of 850cm2/(V·s) is obtained for a 3μm thick GaN film.Gain guided and ridge geometry waveguide laser diodes are fabricated with cleaved facet mirrors at room temperature under pulse current injection.The lasing wavelength is 405.9nm.A threshold current density of 5kA/cm2 and an output light power over 100mW are obtained for ridge geometry waveguide laser diodes.     

量子安全通信探讨

从理论研究、实验进展和技术开发的角度简述了量子安全通信的发展历程;阐述了量子通信的过程.简单介绍了相关的量子安全通信技术:量子密钥、量子认证、量子签名、量子加密算法和量子秘密共享等.分析了阻碍量子安全通信实用化的几个因素,最后对量子安全通信的发展作了展望.     

The Consequences of Water Interactions with Nitrogen-Containing Carbonaceous Quantum Dots—The Mechanistic Studies

Despite the importance of quantum dots in a wide range of biological, chemical, and physical processes, the structure of the molecular layers surrounding their surface in solution remains unknown. Thus, knowledge about the interaction mechanism of Nitrogen enriched Carbonaceous Quantum Dots’ (N-CQDs) surface with water—their natural environment—is highly desirable. A diffusive and Stern layer over the N-CQDs, characterized in situ, reveals the presence of anionic water clusters [OH(H₂O)_n]⁻. Their existence explains new observations: (i) the unexpectedly low adsorption enthalpy (ΔH_ads) in a pressure range below 0.1 p/p_s, and ΔH_ads being as high as 190 kJ/mol at 0.11 p/p_s; (ii) the presence of a “conductive window” isolating nature—at p/p_s below 0.45—connected to the formation of smaller clusters and increasing conductivity above 0.45 p/p_s, (iii) Stern layer stability; and (iv) superhydrophilic properties of the tested material. These observables are the consequences of H₂O dissociative adsorption on N-containing basic centers. The additional direct application of surfaces formed by N-CQDs spraying is the possibility of creating antistatic, antifogging, bio-friendly coatings.     

求解QoS组播路由问题的改进型量子进化算法

QoS组播路由问题是一个非线性的组合优化问题,已证明了该问题是NP完全问题。提出一种将基于量子计算原理的量子进化算法用于此类问题求解的算法,该算法对基本的量子进化算法进行改进,采用进化方程对量子门进行调整,采用量子变异阻止未成熟收敛,使之更适合于QoS组播路由的求解。仿真结果显示,该算法能快速搜索并收敛到全局（近似）最优解,且随着网络规模的增大算法保持了良好的特性,在寻优速度上与解的质量上优于其他进化算法与基本的量子进化算法。     

Various Approaches to Studying the Phase Transition in an Octamethylcyclotetrasiloxane Crystal: From X-ray Structural Analysis to Metadynamics

The structure, thermodynamic parameters, and the character of thermal motion in octamethylcyclotetrasiloxane (D4) were investigated using the combination of experimental (single-crystal X-ray diffraction, thermochemistry) and theoretical (density functional theory calculations, ab initio molecular dynamics and metadynamics) methods. Single crystals of D4 were grown in a glass capillary in situ and the structures of high- (238–270 K) and low-temperature (100–230 K) phases were studied in detail. In the temperature interval 230–238 K, a phase transition with rather low enthalpy (−1.04(7) kcal/mol) was detected. It was found that phase transition is accompanied by change of conformation of cyclosiloxane moiety from boat-saddle (cradle) to chair. According to PBE0/6-311G(d,p) calculation of isolated D4, such conformation changes are characterized by a low barrier (0.07 kcal/mol). The character of molecular thermal motion and the path of phase transition were established with combination of periodic DFT calculations, including molecular dynamics and metadynamics. The effect of crystal field led to an increase in the calculated phase transition barrier (4.27 kcal/mol from low- to high-temperature phase and 3.20 kcal/mol in opposite direction).